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The activity series of metals ranks metals from most reactive to least reactive. Students use it to predict whether a metal will replace another metal ion in a compound. This cheat sheet helps organize the ranking, reaction patterns, and evidence for single-displacement reactions. It is especially useful for balancing equations and deciding when no reaction occurs. A metal higher in the activity series can displace a metal lower in the series from an aqueous compound. Metals above hydrogen can react with acids to produce hydrogen gas, while metals below hydrogen usually do not. These reactions involve electron transfer, so the reacting metal is oxidized and the metal ion or hydrogen ion is reduced. Careful use of the series prevents impossible reaction predictions.

Key Facts

  • A metal higher in the activity series is more reactive and can replace a metal lower in the series from an aqueous ionic compound.
  • The general single-displacement pattern is A+BCAC+BA + BC \rightarrow AC + B when metal AA is more reactive than metal BB.
  • If metal AA is lower than metal BB in the activity series, the reaction A+BCA + BC \rightarrow products does not occur.
  • Metals above hydrogen react with acids to form a salt and hydrogen gas, such as Zn+2HClZnCl2+H2Zn + 2HCl \rightarrow ZnCl_2 + H_2.
  • Metals below hydrogen, such as copper, silver, gold, and platinum, usually do not produce H2H_2 gas with dilute acids.
  • In a successful displacement reaction, the solid metal loses electrons and is oxidized, such as ZnZn2++2eZn \rightarrow Zn^{2+} + 2e^-.
  • The metal ion being displaced gains electrons and is reduced, such as Cu2++2eCuCu^{2+} + 2e^- \rightarrow Cu.
  • A balanced equation must conserve atoms and charge, so 2Al+3CuCl22AlCl3+3Cu2Al + 3CuCl_2 \rightarrow 2AlCl_3 + 3Cu is balanced correctly.

Vocabulary

Activity series
A list of metals arranged from most reactive to least reactive based on their ability to lose electrons.
Single-displacement reaction
A reaction in which one element replaces another element in a compound, often written as A+BCAC+BA + BC \rightarrow AC + B.
Oxidation
The loss of electrons by an atom or ion, such as MgMg2++2eMg \rightarrow Mg^{2+} + 2e^-.
Reduction
The gain of electrons by an atom or ion, such as Ag++eAgAg^+ + e^- \rightarrow Ag.
Spectator ion
An ion that remains unchanged during a reaction and does not take part in the electron transfer.
Hydrogen gas test
A test in which hydrogen gas makes a small pop sound when exposed to a flame, showing that H2H_2 was produced.

Common Mistakes to Avoid

  • Reversing the activity series, which is wrong because only the metal higher on the list can replace a metal lower on the list.
  • Predicting a reaction for every metal and salt mixture, which is wrong because a lower-reactivity metal cannot displace a higher-reactivity metal ion.
  • Forgetting that metals above hydrogen react with acids, which leads to missing products like H2H_2 in equations such as Mg+2HClMgCl2+H2Mg + 2HCl \rightarrow MgCl_2 + H_2.
  • Writing unbalanced formulas or charges, which is wrong because ionic compounds must be electrically neutral, such as AlCl3AlCl_3 rather than AlCl2AlCl_2.
  • Ignoring oxidation and reduction, which hides the electron transfer that explains why the displacement reaction happens.

Practice Questions

  1. 1 Using the activity series, predict whether Zn+CuSO4Zn + CuSO_4 \rightarrow will react. If it reacts, write the balanced chemical equation.
  2. 2 Will Cu+2AgNO3Cu(NO3)2+2AgCu + 2AgNO_3 \rightarrow Cu(NO_3)_2 + 2Ag occur? Explain using relative metal reactivity.
  3. 3 Balance the reaction and identify the gas produced: Mg+HClMgCl2+H2Mg + HCl \rightarrow MgCl_2 + H_2.
  4. 4 A student places silver metal into a solution of Zn(NO3)2Zn(NO_3)_2 and expects zinc metal to form. Explain why this prediction is incorrect.